At this stage, the relationship between the natural ecological environment and economic development has attracted more and more attention, and green innovation has begun to enter people’s vision. For companys, green innovation activities can improve their technical level and reduce production costs, which is conducive to improving resource utilization efficiency and ecological and economic benefits, and is conducive to achieving coordination between people and nature, and between the environment and economic development. Based on this, this article examined the green innovation ability of companies and the concept of sustainable development. Under the background of Artificial Intelligence (AI), strategies to enhance the sustainable development ability such as making decisions by using expert systems have been proposed. The strategy to increase the green innovation ability was put forward, and the impact of the concept of sustainable development on the green innovation ability of companys was studied. The following findings were concluded from the experimental study. In terms of green innovation input capacity, both Company S and Company T, which adhered to the concept of sustainable development, have improved their green innovation input capacity year by year. The green innovation input capacity index of Company S was 4.27% higher than that of Company T. In other aspects, Companys S and T, which adhered to the concept of sustainable development, have improved their green innovation and ecological environmental protection capacity index year by year. The concept of sustainable development that companys adhere to is conducive to enhancing their green innovation capabilities.